Yes, you can paint melamine cover surfaces and if done right it is not a tedious process and it can also be a useful low cost makeover that will do wonders for your kitchens, any other indoor rooms or outdoor spaces for that matter. What's even more fun is that you can now get melamine paint in a large and wide variety of different colours.
It is process that must be followed one step at a time. First of all, one must use a good cleaner to clean the surface. I recommend you use the liquid version, which is not toxic like the powder you have to mix. You can find it in any store that deals with interior products. You can also find these Melamine cover surface cleaners at large surface renovating stores. Make sure you wash it properly all around. Another important benefit of using the liquid is that you won't have to rinse after.
Once you've cleaned the surface to remove any trace of grease, oil, or any other substance, you must then prime the cabinets with oil based primer. Melamine paints are a combination of a urethane product and an oil-based paint. Because the paint is oil-based, it is a little more difficult to work with than other paints and has to be cleaned up using a solvent or paint thinner. These paints take longer to dry than latex paints, but are durable and have the advantage being able to stick to slick surfaces like these.
Mostly there are no stores that provide products such as a melamine primer but oil primer will do the trick as you can paint on top of this with any kind of paint. Once you have cleaned the surface with the primer, you can go ahead and start painting the melamine cover surface with melamine paint. It usually works better with sponge brushes and rollers and goes on much smoother with sponge. You can try Krylon Fusion spray paint. It's formulated to adhere to plastic surfaces. I give it my full, enthusiastic endorsement. I was dubious about its effectiveness at first, but was pleasantly surprised with the results I got from it on a recent project.
Now that the melamine cover board is properly sanded and primer has been applied you can start to paint it. One of the simplest ways is to use a coat of the melamine paint to the board using whichever brush is recommended for the paint you are using. For best results you should apply the paint in a thin layer. Let this first layer of paint dry and then apply another layer of paint as you did previously. Add another coat if you think it is necessary.
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